Mechanism of Cationic Polymerization

Wavelength tunability in photoinitiated cationic polymerization

Onium salts, widely used cationic photoinitiators, have absorption in the short wavelength of the UV spectrum. However, their spectral sensitivity can be tuned up to the visible region by using several methods. Photosensitization of onium salts, their charge transfer complex formation and their free radical promotion are some techniques that are used to provide wavelength flexibility. This chap...

Mechanism of immunoglobulin A polymerization.

Employing mercaptoethylamine as a reducing agent, it was demonstrated by analytical ultracentrifugation and polyacrylamide gel electrophoresis that polymeric immunoglobulin A (IgA) was reduced to a 10 S dimer and 7 S monomer, and that dimer IgA was more resistant to reductive cleavage than the higher polymers. When dimer and monomer IgA were subjected to electrophoresis in polyacrylamide gels i...

Observation of eliminative cationic polymerization within van der Waals clusters

Cyclic Oligomers in the Cationic Polymerization of Heterocycles

The cationic polymerization of heterocyclic monomers may lead to polymers containing substantial, yet Variable amounts of cyclic oligomers. This review gives a survey of the systems where such oligomers have been found. Oligomer formation is generally observed in the polymerization of oxiranes and thiiranes. The most frequently observed oligomers are the cyclic dimers and cyclic tetramers but o...

Preparation of cationic polyacrylamide by aqueous two-phase polymerization

Cationic polyacrylamide (CPAM) was synthesized by aqueous two-phase polymerization technique using acrylamide (AM) and dimethylaminoethyl methacrylate methyl chloride (DMC) as raw materials, aqueous polyethylene glycol 20000 (PEG 20000) solution as dispersant, 2,2′-azobis(2-amidinopropane) dihydrochloride (V-50) as initiator and poly(dimethylaminoethyl methacrylate methyl chloride) (PDMC) as st...